First check if you already have 
GCC (GNU Compiler Collection) installed in your system. Type
 # gcc --version (or 
# which gcc). If not, install it first: 
# yum install gcc or 
# yum install gcc-c++
Next open a text editor (
GEDIT, say) and write your first C program.
# gedit hello.c
The 
hello.c program's source code can be something like
#include <stdio.h>
int main()
{
 printf("Hello World");
 return 0;
}
Next compile  and create an executable file
# gcc hello.c -o hello
Now execute your program
# ./hello